Shaanxi BLOOM Tech Co., Ltd. yog ib tug ntawm cov uas paub txog manufacturers thiab lwm tus neeg ntawm cobalt tpp cas 14172-90-8 nyob rau hauv Suav teb. Txais tos rau cov lag luam wholesale bulk zoo cobalt tpp cas 14172-90-8 muag ntawm no los ntawm peb lub hoobkas. Kev pabcuam zoo thiab tus nqi tsim nyog muaj.
COBALT TPPyog ib tug compound uas muaj cobalt, cov tshuaj formula yog Co(TPP), CAS 14172-90-8. TPP sawv cev rau 4-phenylporphyrin, nws yog polycyclic organic compound, nws cov qauv molecular muaj plaub lub nplhaib benzene thiab lub hauv paus nitrogen atom. Nws yog xim liab. Nws muaj qhov tsis zoo solubility thiab yuav luag insoluble hauv dej. Nws muaj qhov zoo thermal stability ntawm qhov kub thiab txias thiab tuaj yeem tswj tau cov qauv tshuaj lom neeg ruaj khov thiab lub cev muaj zog hauv qee qhov kev kub ntxhov thiab cov txheej txheem cua sov. Nyob rau tib lub sijhawm, qhov no kuj txhais tau hais tias Nws yuav tsum tau npaj thiab ua tiav ntawm qhov kub thiab txias, yog li kev siv cov tshuaj tiv thaiv kub kub tshwj xeeb thiab cov khoom siv yuav tsum tau siv. Tab sis nws tuaj yeem yaj hauv qee cov kuab tshuaj organic, xws li chloroform, benzene thiab toluene, thiab lwm yam. Nws muaj peev xwm siv dav thiab siv ntau yam, xws li catalysts, fluorescent probes, optical material, sensors, thiab bioactive molecules. Nrog rau kev txhim kho txuas ntxiv ntawm thev naus laus zis thiab kev tshawb fawb, daim ntawv thov muaj peev xwm thiab kev cia siab ntawm Nws nyob rau ntau qhov chaw tseem yuav txuas ntxiv nthuav dav thiab tob zuj zus.

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Tshuaj Formula |
C44H30CON4 |
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Exact Mass |
673 |
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Molecular Luj |
674 |
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m/z |
673 (100.0%), 674 (47.6%), 675 (11.1%), 674 (1.5%) |
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Elemental Analysis |
C, 78,45; H, 4,49; coj, 8,75; 8.32 Nws |
COBALT TPP(cobalt tetraphenylporphyrin) yog ib tug macromolecular qauv tsim los ntawm plaub phenylporphyrin pawg thiab ib tug cobalt atom. Nws muaj cov qauv molecular ntawm C44H30CoN4 thiab molecular hnyav ntawm 678.57 g / mol. Cov qauv molecular ntawm qhov sib xyaw no tau raug tshawb fawb thiab tshuaj xyuas.
Siv cov txheej txheem xws li X-ray crystallography, cov kws tshawb fawb tau txiav txim siab cov qauv molecular ntawm cov khoom. Nws cov qauv molecular yog symmetrical thiab octagonal, muaj plaub pawg phenylporphyrin thiab lub hauv paus cobalt atom. Nyob rau hauv lub dav hlau ntawm cov khoom molecule, plaub pawg phenylporphyrin yog tag nrho cov txheej txheem nyob rau hauv tib lub dav hlau, thiab txais yuav ib tug π-electron conjugated qauv zoo ib yam li npib tsib xee los yog tooj liab porphyrin compounds. Cov qauv molecular no ua rau nws muaj hluav taws xob zoo conductivity thiab catalytic zog.

Tsis tas li ntawd, cov qauv molecular ntawm nws kuj qhia tau qee yam ntxwv ntsig txog phenylporphyrins. Piv txwv li, cobalt atom nyob rau hauv nws molecule yog nyob rau hauv ib tug loj porphyrin dav hlau ncig los ntawm plaub pawg phenylporphyrin. Qhov kev teeb tsa no ua rau nws muaj kev ruaj ntseg zoo thiab photosensitivity, thiab dav siv hauv biology thiab tshuaj.
Zuag qhia tag nrho, cov qauv molecular ntawm nws muaj cov yam ntxwv ntawm cov phenylporphyrin compounds, thiab vim hais tias nws muaj cobalt caij, nws muaj zoo hluav taws xob conductivity thiab catalytic zog, thiab kev tshawb fawb thiab kev soj ntsuam ntawm nws cov qauv molecular yuav pab ntxiv kev txhim kho tsim ib tug ntau npaum ntawm nws daim ntawv thov.

COBALT TPPyog cobalt-muaj cov khoom xyaw uas muaj peev xwm siv tau ntau yam.
1. Raws li kev sojntsuam fluorescent:
Nws kuj tseem siv tau los ua fluorescent sojntsuam hauv kev ua liaj ua teb thiab chemistry. Cov kws tshawb fawb pom tias Nws muaj cov khoom fluorescence zoo thiab tuaj yeem kuaj xyuas cov khoom xws li ions, molecules thiab cov proteins hauv cov qauv lom neeg los ntawm cov txheej txheem tshuaj fluorescence. Tsis tas li ntawd, Nws tseem tuaj yeem cuam tshuam nrog DNA thiab lwm yam macromolecules lom, muab txoj kev tshawb nrhiav tshiab thiab kev tshuaj xyuas.
2. Raws li cov khoom siv kho qhov muag:
Vim nws cov qauv molecular tshwj xeeb thiab cov qauv tshwj xeeb, nws tuaj yeem siv los ua cov khoom siv optoelectronic tseem ceeb rau kev tsim thiab tsim cov khoom siv optoelectronic. Kev tshawb fawb tau pom tias nws tuaj yeem tswj hwm nws cov khoom siv kho qhov muag thiab hluav taws xob los ntawm kev siv tshuaj thiab lub cev sib txawv, xws li nqus spectroscopy, fluorescence spectroscopy, conductivity, thiab lwm yam. Cov yam ntxwv no ua rau nws muaj peev xwm siv dav hauv thaj chaw xws li hnub ci hlwb, lub teeb organic-emitting diodes, sensors, thiab quantum xam.
3. Raws li ib tug sensor:
Nws kuj tseem siv tau los ua qhov siab -rhiab sensor hauv thaj chaw ntawm chemistry, biology, thiab kev saib xyuas ib puag ncig. Nws tuaj yeem ua tiav qhov kev xav tau los ntawm kev sib cuam tshuam nrog lub hom phiaj molecules lossis ions, xws li kev lees paub tshuaj lom neeg, adsorption, tshuaj tiv thaiv, kev hloov pauv, thiab lwm yam. Kev tshawb fawb tau pom tias nws tuaj yeem siv los txheeb xyuas cov teeb meem hlau ions hauv cov dej ib puag ncig, cov protein thiab cov hlwb hauv cov qauv tshuaj lom neeg, nrog cov kev xaiv ntawm molecular siab thiab rhiab heev.
4. Raws li bioactive molecules:
Nws tseem tuaj yeem siv rau kev tshawb fawb thiab kev siv hauv kev kho mob thiab biology. Cov kev tshawb fawb tau pom tias Nws tuaj yeem cuam tshuam nrog ntau yam ntawm cov kab mob lom macromolecules, xws li cov protein thiab DNA. Tsis tas li ntawd, Nws kuj tseem tuaj yeem muaj cov tshuaj tiv thaiv - qog, tshuaj tua kab mob, tiv thaiv - oxidative thiab tiv thaiv - inflammatory kab mob lom los ntawm catalysis, oxidation thiab kev tswj ntawm cell membrane permeability. Cov khoom no ua rau Nws muaj kev thov dav dav hauv kev txhim kho tshuaj tshiab thiab kev tshawb fawb biomedical.

Meso tetraphenylporphyrin hlau complexes (MTPR, M=Zn2, Co2) yog porphyrin compounds uas muaj hlau chaw, dav siv nyob rau hauv catalysis, photocatalysis, thiab lom daim ntawv lo. Nws cov qauv tsim muaj xws li porphyrin rings thiab cov chaw sib koom ua ke rau cov hlau sib txawv, nrog rau cov hlau ions xws li zinc (Zn2+) thiab cobalt (Co2+).
Molecular Structure thiab yam ntxwv:
(1) Porphyrin nplhaib qauv:
Porphyrin yog ib qho macrocyclic compound uas muaj plaub nitrogen atoms thiab tuaj yeem koom tes nrog cov hlau ions. Cov qauv ntawm tetraphenylporphyrin (TPP) yog ib qho chaw nyob rau hauv uas plaub txoj hauj lwm ntawm lub nplhaib porphyrin hloov los ntawm phenyl pawg, qhov twg phenyl pawg yog ib tug derivative ntawm benzene nplhaib. Cov qauv no endows porphyrins nrog ib tug loj π - conjugated system, muab lawv zoo heev zog nyob rau hauv lub teeb absorption thiab electron hloov.
(2) Hlau kev sib koom tes:
Hauv meso tetraphenylporphyrin, ammonia atom ntawm lub nplhaib porphyrin ua haujlwm nrog cov hlau ions (xws li Zn2, Co2 *) los tsim cov metalloporphyrin complexes ruaj khov. Hlau ions muab kev ua haujlwm catalytic rau cov hlau hauv nruab nrab thiab tuaj yeem tswj cov khoom hluav taws xob ntawm porphyrins.
Zn2+ yog ib hom hlau ion uas tuaj yeem txhim kho kev ruaj ntseg photochemical ntawm porphyrins thiab ua lub luag haujlwm txhawb nqa hauv cov tshuaj tiv thaiv photocatalytic.
Thaum Co2+ ua raws li lub chaw hlau, nws muaj peev xwm lees txais hluav taws xob muaj zog thiab tuaj yeem ua lub luag haujlwm hauv catalyzing oxygen txo cov tshuaj tiv thaiv.
txheej txheem hluavtaws
Synthesis ntawm Metalloporphyrin:
Lub synthesis ntawm meso tetraphenylporphyrin hlau complexes feem ntau pib los ntawm tetraphenylporphyrin (TPP), uas yog metalized los ntawm reacting nrog hlau ntsev xws li ZnCh los yog CoCH2. Cov txheej txheem no feem ntau yog ua tiav hauv kev daws teeb meem thiab kev sib koom tes ntawm cov hlau yog tswj los ntawm kev kho cov pH thiab kub ntawm cov tshuaj.
Synthesis cov kauj ruam:
1. Ua ntej, synthesize tetraphenylporphyrin (TPP), uas feem ntau tau los ntawm phenylated porphyrin tshuaj tiv thaiv.
2. Sib tov TPP nrog cov khoom siv hlau (xws li ZnCl lossis CoClz) hauv cov kuab tshuaj uas tsim nyog, thiab ua kom sov los yog do hauv qee qhov xwm txheej los tsim kev sib koom tes ntawm cov hlau ion thiab ammonia atom ntawm lub nplhaib porphyrin.
3. Tau txais meso tetraphenylporphyrin hlau complexes (xws li ZnTPP lossis COTPP).

COBALT TPP(cobalt tetraphenylporphyrin) yog ib qho nyuaj uas muaj plaub pawg phenylporphyrin thiab cobalt atom. Hauv nws lub npe, COBALT sawv cev rau cov ntsiab lus cobalt hauv nws, thiab TPP sawv cev rau plaub pawg phenylporphyrin hauv nws. Lub npe zaj dab neeg ntawm no compound hnub rov qab mus rau 1950s.
Thaum ntxov xyoo 1950, American chemist Robin Ganellin synthesized nws thiaj li kawm txog cov tshuaj lom neeg muaj zog metalloporphyrin. Yav dhau los, Ganellin thiab lwm cov kws tshawb fawb tau tsim cov porphyrin derivatives thiab pom tias qee qhov muaj cov khoom zoo ib yam li cov xim ntuj chlorophyll thiab heme. Xav tias cov tebchaw no yuav muaj kev siv tshuaj lom neeg thiab kev kho mob tseem ceeb, lawv tau npaj los ua porphyrins ntau dua.
Ganellin thiab nws cov npoj yaig ntsib ntau yam teeb meem thaum sim ua kom cov porphyrins tshiab. Lawv pom tias feem ntau porphyrins tsis ruaj khov thiab muaj kev cuam tshuam rau cov tshuaj tiv thaiv xws li oxidation lossis degradation. Yog li ntawd, lawv tau pib tshawb nrhiav ib qho chaw ruaj khov porphyrin, thiab thaum kawg tau tsim nws.
Txhawm rau muab lub npe tshiab, Ganellin thiab nws cov npoj yaig tau txiav txim siab ntau lub npe xaiv. Thaum kawg, lawv tau txiav txim siab rau lub npe nws, thiab lawv tau muab npe rau hauv xyoo 1955. Txij thaum ntawd los, nws tau dhau los ua ib qho tseem ceeb ntawm cov khoom siv rau kev kawm ntawm metalloporphyrin compounds, thiab tau siv dav hauv biology, tshuaj, optoelectronics thiab lwm yam.
Cov kev mob tshwm sim ntawm cov tshuaj no yog dab tsi?
Cov yam ntxwv yooj yim
COBALT TPP,Meso tetraphenylporphyrin cobalt (TPCo) yog porphyrin compound uas muaj cobalt ions. Porphyrins yog ib chav kawm ntawm cov organic tebchaw nrog cov qauv tshwj xeeb thiab cov khoom, dav dav hauv cov xwm txheej, xws li chlorophyll thiab heme. Lawv feem ntau muaj lub teeb pom kev zoo thiab cov khoom siv photochemical, yog li lawv muaj ntau yam kev siv hauv optics, electronics, biomedical thiab lwm yam.
TPPCo, raws li hom porphyrin compound, kuj muaj cov yam ntxwv no. Tsis tas li ntawd, vim nws lub hauv paus hlau ion yog cobalt ion, nws kuj tseem tuaj yeem pom qee yam khoom muaj feem xyuam nrog cobalt ion. Piv txwv li, cobalt ions muaj qhov tshwj xeeb hloov kho hauv cov hlau nplaum, uas ua rau TPPCo muaj qee qhov kev cia siab rau hauv kev tshawb fawb ntawm cov khoom sib nqus.
Tej yam tshwm sim lom thiab kev phiv tshuaj speculation
Porphyrin compounds muaj cov khoom nqus dej hauv thaj chaw pom lub teeb, yog li thaum lawv nkag mus rau cov kab mob, lawv tuaj yeem nqus lub teeb lub zog thiab tsim cov tshuaj tiv thaiv photochemical. Cov tshuaj tiv thaiv no tuaj yeem ua rau muaj kev nce ntxiv hauv photosensitivity ntawm cov ntaub so ntswg lom, yog li ua rau photosensitivity tshwm sim. Cov tsos mob ntawm photosensitive tej zaum yuav muaj xws li daim tawv nqaij liab, khaus, stinging, thiab lwm yam, thiab nyob rau hauv mob hnyav, tej zaum yuav ua rau cov tawv nqaij kub hnyiab los yog phototoxic tshuaj. Rau TPPCo, vim nws cov qauv porphyrin, kuj tseem muaj peev xwm ua rau cov tshuaj tiv thaiv photosensitive.
Cov tshuaj lom ntawm cobalt ions
Cobalt ions yog ib hom hnyav hlau ion nrog qee yam tshuaj lom. Thaum cobalt ions nkag mus rau hauv lub cev, lawv yuav khi nrog biomolecules xws li cov proteins thiab enzymes, yog li cuam tshuam nrog lawv cov haujlwm ib txwm muaj. Cov tshuaj lom ntawm cobalt ions tuaj yeem tshwm sim raws li ntau yam tsos mob, xws li xeev siab, ntuav, raws plab, mob plab, thiab lwm yam kab mob hauv plab; Mob taub hau, kiv taub hau, insomnia thiab lwm yam kab mob neurological; Thiab cov tsos mob ntawm cov ntshav thiab zis xws li anemia thiab lub raum tsis ua haujlwm. Rau TPPCo, vim nws cov ntsiab lus cobalt ion, kuj tseem muaj peev xwm ua rau cobalt ion toxicity. Txawm li cas los xij, qhov tshwj xeeb ntawm toxicity thiab cov tsos mob yuav nyob ntawm seb yam xws li cov ntsiab lus ntawm cobalt ions, lub peev xwm metabolic ntawm lub cev, thiab lub sij hawm raug.
Porphyrin compounds muaj lipophilicity thiab yooj yim khi rau cov kab mob lom, hloov lawv cov qauv thiab kev ua haujlwm. Cov nyhuv no tuaj yeem ua rau muaj kev nce ntxiv hauv cov permeability ntawm cov kab mob lom, uas ua rau muaj qhov tsis txaus ntawm cov khoom hauv thiab sab nraud ntawm tes thiab cellular puas. Rau TPPCo, vim nws cov qauv porphyrin, kuj tseem muaj peev xwm ua rau cov kab mob lom. Qhov kev puas tsuaj no tuaj yeem tshwm sim raws li cov tsos mob xws li nce cell membrane permeability, cell o, thiab cell lysis.
Oxidative stress thiab dawb radical puas
Porphyrin tebchaw tuaj yeem tsim cov dawb radicals thiab lwm hom pa oxygen reactive nyob rau hauv lub teeb, uas muaj zog oxidizing zog thiab tuaj yeem ua rau puas tsuaj rau biomolecules xws li cov proteins, lipids, thiab DNA hauv cov kab mob muaj sia. Oxidative stress yog hais txog qhov tsis sib xws ntawm kev tsim khoom thiab kev tshem tawm ntawm ROS hauv cov kab mob, uas tuaj yeem ua rau muaj kev puas tsuaj ntawm tes thiab kev ua haujlwm tsis zoo. Rau TPPCo, vim nws cov qauv porphyrin thiab muaj peev xwm tsim ROS nyob rau hauv lub teeb, kuj tseem muaj peev xwm ua rau muaj kev ntxhov siab oxidative thiab dawb radical puas. Hom kev puas tsuaj no tuaj yeem tshwm sim raws li cov tsos mob xws li protein denaturation, lipid peroxidation, thiab DNA puas.
Porphyrin compounds, raws li chav kawm ntawm cov organic tebchaw nrog cov qauv tshwj xeeb thiab cov khoom, tuaj yeem cuam tshuam cov txheej txheem metabolic hauv cov kab mob. Piv txwv li, lawv tuaj yeem khi rau cov enzymes hauv lub cev thiab hloov lawv txoj haujlwm, yog li cuam tshuam rau cov txheej txheem metabolic thiab cov nqi ntawm lub cev. Rau TPPCo, vim nws cov qauv porphyrin, kuj tseem muaj peev xwm cuam tshuam nrog cov metabolism hauv roj ntsha. Qhov kev cuam tshuam no tuaj yeem tshwm sim raws li cov tsos mob xws li kev hloov pauv hauv cov txheej txheem metabolic, txo qis lossis nce metabolic. Txawm li cas los xij, cov teebmeem metabolic tshwj xeeb tuaj yeem nyob ntawm cov yam ntxwv xws li qhov siab ntawm TPPCo, lub sijhawm raug, thiab hom metabolic ntawm lub cev.
Immune thiab Allergic Reactions
Thaum cov tebchaw txawv teb chaws nkag mus rau hauv lub cev, lawv tuaj yeem ua rau lub cev tiv thaiv kab mob lossis ua xua. Cov tshuaj tiv thaiv no feem ntau tshwm sim los ntawm cov kab mob pom thiab tawm tsam cov tebchaw txawv teb chaws. Rau TPPCo, raws li nws yog ib qho chaw txawv teb chaws, kuj tseem muaj peev xwm ua rau lub cev tiv thaiv kab mob lossis kev tsis haum tshuaj. Cov tshuaj tiv thaiv no yuav tshwm sim raws li cov tsos mob xws li pob khaus, khaus, ua tsis taus pa, poob siab, thiab lwm yam. Txawm li cas los xij, hom thiab qib ntawm kev tiv thaiv kab mob yuav nyob ntawm seb tus neeg mob lub cev tiv thaiv kab mob, koob tshuaj tiv thaiv kab mob, thiab hom kis tau tus mob.
Muaj tshwm sim tshwj xeeb
Ntxiv rau cov kev mob tshwm sim dav dav uas tau hais los saum no, TPPCo kuj tseem muaj qee qhov kev mob tshwm sim tshwj xeeb. Cov kev mob tshwm sim no yuav cuam tshuam rau lawv cov qauv tshuaj lom neeg, kev ua haujlwm lom neeg, lossis hom kev thov.
Toxic cuam tshuam rau qee yam kabmob
Tej yam tshuaj tej zaum yuav muaj tshuaj lom rau ntawm lub cev. Rau TPPCo, yog tias nws tau noj thiab khaws cia rau hauv ib qho khoom nruab nrog cev, nws yuav muaj kev phom sij rau lub cev. Piv txwv li, yog tias TPPCo accumulates hauv daim siab, nws yuav ua rau lub siab ua haujlwm puas tsuaj; Yog tias nws khaws cia rau hauv lub raum, nws tuaj yeem ua rau lub raum tsis ua haujlwm.
Genetic toxicity
Qee cov tshuaj yuav ua rau muaj kev puas tsuaj rau cov khoom siv caj ces ntawm cov kab mob, xws li DNA, ua rau muaj tshuaj lom neeg. Rau TPPCo, yog tias nws tuaj yeem khi rau DNA thiab ua rau muaj kev puas tsuaj, nws yuav muaj cov tshuaj toxicity. Cov tshuaj toxicity no tuaj yeem ua rau kev hloov pauv caj ces, chromosomal txawv txav, thiab lwm yam teeb meem caj ces, uas tuaj yeem cuam tshuam rau kev loj hlob thiab kev ruaj ntseg ntawm cov kab mob.
Carcinogenicity
Tej yam tshuaj tej zaum yuav yog carcinogenic nyob rau hauv ntev los yog siab - koob tshuaj. Rau TPPCo, yog tias nws raug pov thawj tias yog carcinogenic, nws yuav ua rau muaj kev hem thawj rau tib neeg kev noj qab haus huv. Txawm li cas los xij, tej zaum yuav muaj kev tshawb fawb me me ntawm cov carcinogenicity ntawm TPPCo tam sim no, yog li nws tsis tuaj yeem txiav txim siab seb nws puas yog carcinogenic.
Qhov cuam tshuam rau lub cev xeeb tub
Tej yam tshuaj tej zaum yuav muaj kev cuam tshuam rau cov kab mob ntawm cov kab mob, ua rau cov me nyuam tsis ua hauj lwm los yog kev ua me nyuam toxicity. Rau TPPCo, yog tias nws tau raug pov thawj tias muaj tshuaj lom rau ntawm lub cev xeeb tub, nws yuav muaj kev cuam tshuam rau tib neeg fertility thiab cov xeeb ntxwv noj qab haus huv. Txawm li cas los xij, tej zaum yuav muaj kev tshawb fawb me me ntawm cov teebmeem ntawm TPPCo ntawm lub cev xeeb tub, ua rau nws nyuaj rau kev txiav txim siab seb nws puas muaj cov tshuaj lom menyuam yaus.
ua faq
Dab tsi yog cobalt phthalocyanine?
Cobalt phthalocyanine (CoPc) yogib tug paub electrocatalyst rau carbon dioxide txo cov tshuaj tiv thaiv (CO2RR)uas, thaum adsorbed rau ntawm ntug- dav hlau graphite (EPG) electrodes, qhia me ntsis kev ua si thiab xaiv rau CO ntau lawm nrog rau co- tiam H2.
Bis triphenylphosphine cobalt chloride yog dab tsi?
Bis (triphenylphosphine) cobalt (II) chloride muajtseem ceeb antioxidant kev ua, raws li nws muaj peev xwm tshem tawm dawb radicals los ntawm lwm yam molecules. Nws kuj muaj qhov tseem ceeb los tiv thaiv- cov khoom mob qog noj ntshav vim nws muaj peev xwm tua cov qog nqaij hlav cancer los ntawm kev ua rau DNA tawg thiab inhibiting qog loj hlob.
Dab tsi yog cobalt ammonium phosphate siv rau?
Cobaltous ammonium phosphate yog siv los ua ib qho kev hloov pauv tsis zoo ntawm cobalt violet pigments. Nws yogsiv los ua cov xim pleev xim rau hauv cov xim, iav, glazes, enamels thiab plastics.
Kev noj qab haus huv ntawm Ca3P2 yog dab tsi?
Cim npe nrov: cobalt tpp cas 14172-90-8, lwm tus neeg, manufacturers, hoobkas, lag luam wholesale, yuav, nqe, tej, kev muag khoom




